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Compounds of formula I according to claim 1 in which Het is chosen from rings which are pyrrolyl optionally substituted by one or more alkyl, phenyl or phenylalkyl radicals, pyridyl optionally substituted by one or more alkyl, phenyl or phenylalkyl radicals, pyrimidinyl optionally substituted by one or more alkyl, phenyl or phenylalkyl radicals, imidazolyl optionally substituted by one or more alkyl, phenyl or phenylalkyl radicals, thiazolyl optionally substituted by one or more alkyl, phenyl or phenylalkyl radicals, oxazolinyl optionally substituted by one or more alkyl, phenyl or phenylalkyl radicals, thiazolinyl optionally substituted by one or more alkyl, phenyl or phenylalkyl radicals, pyrazinyl optionally substituted by one or more alkyl, phenyl or phenylalkyl radicals, tetrazolyl optionally substituted by one or more alkyl, phenyl or phenylalkyl radicals or triazolyl optionally substituted by one or more alkyl, phenyl or phenylalkyl radicals.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes an N-alk or CH-R6 radical, R6 denotes a hydrogen atom and R3 denotes an alkoxycarbonyl radical with the exception of tert-butoxycarbonyl, characterized in that a derivative of formula: Process for the preparation of compounds of formula I according to claim 1, in which R denotes an N-alk or CH-R6 radical, R6 denotes a hydrogen atom and R3 denotes a tert-butoxycarbonyl radical, characterized in that isobutene is reacted with a corresponding compound of formula I in which R denotes an N-alk or CH-R6 radical, R6 denotes a hydrogen atom and R3 denotes a carboxyl radical, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes an N-alk or CH-R6 radical, R6 denotes a hydrogen atom and R3 denotes a carboxyl radical, characterized in that a derivative of formula: Process for the preparation of compounds of formula I according to claim 1, in which R denotes an N-alk or CH-R6 radical, R6 denotes a hydrogen atom and R3 denotes a carboxamido radical, characterized in that a derivative of formula: Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical, R4 denotes an alkyl, -alk-Het or phenylalkyl radical in which the phenyl nucleus is optionally substituted by one or more substituents chosen from halogen atoms and alkyl, alkoxy, nitro, amino, hydroxyl, cyano, -alk-NH2, -COOR10 and -alk-COOR10 radicals and R5 is identical with R4, characterized in that a corresponding compound of formula I in which R denotes a CH-R6 radical and R6 denotes a hydrogen atom is reacted with a halide of formula Hal-Rg, in which Rg denotes an alkyl, -alk-Het or phenylalkyl radical in which the phenyl nucleus is optionally substituted by one or more substituents chosen from halogen atoms and alkyl, alkoxy, nitro, amino, hydroxyl, cyano, -alk-NH2, -COOR10 and -alk-COOR10 radicals, alk, Het and R10 having the same meanings as in claim 1, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical and R4 and R5 form, with the carbon atom to which they are attached, a cycloalkyl radical, characterized in that a corresponding compound of formula I in which R denotes a CH-R6 radical and R6 denotes a hydrogen atom is reacted with a derivative of formula Hal-alk-Hal in which Hal denotes a halogen atom and alk denotes an alkyl C radical, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical in which R5 denotes an -NR8R9 radical and R8 and R9 denote hydrogen atoms, characterized in that a halide Hal-R4 in which Hal denotes a halogen atom and R4 has the same meanings as in claim 1 is reacted with a corresponding compound of formula I in which R denotes a CH-R6 radical, R6 denotes an -NR14R15 radical, R14 denotes a hydrogen atom, R15 denotes a -COR22 radical and R22 denotes an alkyl radical 1 C , followed by a hydrolysis, the product is isolated and is optionally converted into salt.

Michel Sardou - La Maladie d'amour lyrics + English translation (Version #2)

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical in which R5 denotes an -NR8R9 radical, R9 denotes a hydrogen atom and R8 denotes an alkyl, -alk-COOR10, -alk-NR10R21, -alk-Het or phenylalkyl radical in which the phenyl nucleus is optionally substituted, characterized in that a corresponding compound of formula I in which R denotes a C R4 R5 radical, R5 denotes an -NR8R9 radical and R8 and R9 denote hydrogen atoms is reacted with a halide Hal-R8 in which R8 has the same meanings as above, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical in which R5 denotes an -NR8R9 radical, R9 denotes a hydrogen atom or an alkyl radical and R8 denotes an alkyl C radical, characterized in that a corresponding compound of formula I in which R denotes a C R4 R5 radical, R5 denotes an -NR8R9 radical, R9 denotes a hydrogen atom or an alkyl radical and R8 denotes a hydrogen atom is reacted with an acyl C halide, followed by reduction of the product obtained, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical in which R5 denotes an -NR8R9 radical and R9 denotes an alkyl radical, characterized in that a corresponding compound of formula I in which R denotes a C R4 R5 radical, R5 denotes an -NR8R9 radical, R8 has the same meanings as in claim 1 and R9 denotes a hydrogen atom is reacted with a derivative of the formula Hal-alk in which Hal denotes a halogen atom and alk denotes an alkyl radical, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical in which R5 denotes an -NR8R9 radical, R9 denotes a hydrogen atom or an alkyl radical and R8 denotes a - C alk-NR10R21 radical, characterized in that a derivative of formula: Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical in which R5 denotes a -COOR10 radical and R10 denotes a hydrogen atom, characterized in that a corresponding compound of formula I in which R denotes a C R4 R5 radical in which R5 denotes a -COOR10 radical and R10 denotes an alkyl radical is hydrolysed, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical in which R5 denotes a -COOR10 radical and R10 denotes an alkyl radical, characterized in that a corresponding compound of formula I in which R denotes a CH-R6 radical and R6 denotes an alkyl, -alk-Het or optionally substituted phenylalkyl radical is reacted with a halide of formula Hal-COOR10 in which R10 denotes an alkyl radical and Hal denotes a halogen atom, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical in which R5 denotes an -alk-COOR10 radical, characterized in that a corresponding compound of formula I in which R denotes a CH-R6 radical, R6 denotes an -alk-COOR10 radical and R10 has the same meanings as in claim 1 is reacted with a halide Hal-R4 in which R4 has the same meanings as in claim 1, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 in which R5 denotes an -alk-CN radical in which alk contains 1 carbon atom, characterized in that sodium cyanide is reacted with a derivative of formula: Process for the preparation of compounds of formula I according to claim 1 in which R denotes a C R4 R5 radical in which R5 denotes a - C alkOH radical, characterized in that COCl 2 is reacted with a corresponding compound of formula I in which R denotes a C R4 R5 radical in which R5 denotes an -alk-COOR10 radical and R10 denotes a hydrogen atom, followed by a reduction, the product is isolated and is optionally converted into salt.

Esprit D'Amour — Lolita 1997 - Dominique Swain - Polyvore

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical in which R5 denotes a - 1 C alkOH radical, characterized in that trimethylsilane chloride is reacted with a derivative of formula: Process for the preparation of compounds of formula I according to claim 1, in which R denotes a C R4 R5 radical in which R5 denotes a 1-pyrrolyl radical optionally substituted by a -COOR10 radical, characterized in that a derivative of formula: Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CH-R6 radical in which R6 denotes an alkyl C or phenylalkyl radical in which the phenyl nucleus is optionally substituted by one or more substituents chosen from halogen atoms and alkyl, alkoxy, nitro, amino, hydroxyl, cyano, -alk-NH2, -COOR10 and -alk-COOR10 or -alk-Het radicals, characterized in that a derivative of formula: Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CH-R6 radical in which R6 denotes an optionally substituted phenylalkyl or -alk-Het radical, characterized in that a corresponding compound of formula I in which R denotes a CH-R6 radical and R6 denotes a hydrogen atom is reacted with a halide of the formula Hal-Rp in which Rp denotes a phenylalkyl radical in which the phenyl nucleus is optionally substituted by one or more substituents chosen from halogen atoms and alkyl, alkoxy, nitro, amino, hydroxyl, cyano, -alk-NH2, -COOR10 and -alk-COOR10 or -alk-Het radicals in which alk, Het and R10 have the same meanings as in claim 1, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CHR6 radical and R6 denotes a - C alk-OH radical, characterized in that a derivative of formula: Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CH-R6 radical in which R6 denotes an -NR14R15 radical and each of R14 and R15 denotes a hydrogen atom, characterized in that a corresponding compound of formula I in which R denotes a CH-R6 radical in which R6 denotes an -NR14R15 radical, R14 denotes a hydrogen atom, R15 denotes a -COR22 radical and R22 denotes an alkyl radical is hydrolysed, followed in the case of the compounds in which R3 denotes an alkoxycarbonyl radical by an esterification of the corresponding acid, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CH-R6 radical, R6 denotes an -alk-NR14R15 radical and each of R14 and R15 denotes a hydrogen atom with the exception of those in which R3 denotes a carboxamido radical, characterized in that bromine and sodium hydroxide are reacted with a corresponding compound of formula I in which R denotes a CH-R6 radical, R6 denotes an -alk-CONR10R21 radical and R10 and R21 denote hydrogen atoms, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CH-R6 radical, R6 denotes an -alk-NR14R15 radical, each of R14 and R15 denotes a hydrogen atom and R3 denotes a carboxamido radical, characterized in that ammonia is reacted with a corresponding compound of formula I in which R denotes a CH-R6 radical, R6 denotes an -alk-NR14R15 radical, each of R14 and R15 denotes a hydrogen atom and R3 denotes an alkoxycarbonyl radical, the product is isolated and is optionally converted into salt.

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Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CH-R6 radical and R6 denotes an -alk-COOR10 radical, characterized in that a corresponding derivative of formula: Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CH-R6 radical and R6 denotes an -alk-CO-NR10R21 radical, characterized in that a corresponding compound of formula I in which R denotes a CH-R6 radical and R6 denotes an -alk-COOR10 radical, alk having the same meaning as in claim 1, and R10 denotes a hydrogen atom or an alkyl radical is reacted with an amine HNR10R21 in which R10 and R21 have the same meanings as in claim 1, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CH-R6 radical and R6 denotes an -RCOOR10 radical, characterized in that a corresponding compound of formula I in which R denotes a CH-R6 radical and R6 denotes a hydrogen atom is reacted with a derivative of formula OHC- C alk-COOR10 in which alk and R10 have the same meanings as in claim 1, the product is isolated and is optionally converted into salt. Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CH-R6 radical and R6 denotes a 1-pyrrolyl radical optionally substituted by a -COOR10 radical, characterized in that a corresponding compound of formula I in which R denotes a CH-R6 radical and R6 denotes an -NR14R15 radical and R14 and R15 denote hydrogen atoms is reacted with a derivative of formula: Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CH-R6 radical and R6 denotes a -COOalk radical, characterized in that an inorganic acid is reacted with a derivative of formula: Process for the preparation of compounds of formula I according to claim 1, in which R3 denotes a carboxyl radical, characterized in that a corresponding compound of formula I in which R3 denotes an alkoxycarbonyl radical is hydrolysed, the product is isolated and is optionally converted into salt.

Process for the preparation of compounds of formula I according to claim 1, in which R denotes a CH-R6 radical and R6 denotes a 2-oxo-2,5-dihydro-pyrrolyl radical, characterized in that a corresponding compound of formula I in which R denotes a CH-R6 radical, R6 denotes an -NR14R15 radical and R14 and R15 denote hydrogen atoms is reacted with 2,5-dimethoxy-2,5-dihydrofuran, the product is isolated and is optionally converted into salt.

Medications containing, as active principle, at least one compound of formula I according to one of claims 1, 2 and 63 or a salt of such a compound.

The present invention relates to compounds of formula: